Here's the original image....
Some images are just begging to be turned to black and white (for me anyway) and this was one of them. Whilst I like the red jumper, the background of the toys was distracting and competing with her eyes.
I opened the image in lightroom 3 and played with the exposure, contrast and also applied a preset called NKYF Subdued from Abby's Presets which I cannot find a source for at the moment. I also cropped the image in tight.
A quick tidy up in Photoshop of her skin, eyes and a few blemishes and here is the end result.